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    ASTM A193/A193M Grade B5 Stud Bolts – UNS S50100

    5% chromium martensitic stainless steel stud bolts for high-temperature, high-pressure bolting in refinery hydrogen and hot corrosion service environments.

    ASTM A193/A193M Grade B5 Stud Bolts are manufactured from UNS S50100, a 5% chromium martensitic stainless steel alloy that provides a combination of elevated-temperature strength, hardness, and moderate corrosion resistance superior to carbon steel grades but without the austenitic microstructure of the B8 series. The martensitic structure, achieved through appropriate heat treatment, enables Grade B5 to deliver significantly higher hardness and tensile strength compared to austenitic stainless grades of similar size, while the 5% chromium content provides meaningful resistance to oxidation, sulfidation, and corrosion in hot process streams containing hydrogen, hydrogen sulfide, and other refinery gases at elevated temperatures. ASTM A193 specifies a maximum hardness limit for Grade B5 to provide assurance against hydrogen-induced stress corrosion cracking in hydrogen service environments, which is a critical safety consideration for refinery applications. These stud bolts are widely used in flange bolting on hot oil service, catalytic reformer reactors, hydrocracker units, and crude distillation columns across the petroleum refining and petrochemical processing industries.

    ASTM A193/A193M Grade B5 Chemical Composition - Ferritic Steels

    Grade Description and
    UNS Designation
    C Mn P S Si Cr Mo
    ASTM A193 Grade B5 5% Cr 0.10 min 1.00 0.040 0.030 1.00 4.0-6.0 0.40-0.65
    Product Analysis VariationB 0.01 0.03 0.005 0.005 0.05 0.10 0.05

    ASTM A193/A193M Grade B5 Mechanical Requirements - Ferritic Steels (Inch)

    Grade Diameter, in. Minimum Tempering
    Temperature,
    °F
    Tensile Strength, min, ksi Yield Strength, min, 0.2 %
    offset, ksi
    Elongation in 4D, min, % Reduction of Area, min, %Reduction of Area, min, % Hardness,
    max
    ASTM A193 Grade B5 up to 4, incl 1100 100 80 16 50 . . .

    ASTM A193/A193M Grade B5 Mechanical Requirements - Ferritic Steels (Metric)

    Class Diameter,
    [mm]
    Min.Tempering
    Temp. °C
    Tensile Strength,
    min, MPa
    Yield Strength,min,
    .2% offset, MPa
    Elongation in 4D,
    min, %
    Reduction of Area, min, % Hardness,
    max
    ASTM A193 Grade B5 up to M100, incl 593 690 550 16 50 . . .

    ASTM A193/A193M Grade B5 Bolting Components Marking - Ferritic Steels

    Grade Grade Symbol
    ASTM A193 Grade B5 TB B5

    Frequently Asked Questions

    What is ASTM A193 Grade B5?
    ASTM A193 Grade B5 is a bolting material covering 5% Cr-Mo (UNS S50100). Used in high-temperature, high-pressure flange, pressure-vessel and heat-exchanger bolting service per ASTM A193/A193M.
    What is the UNS designation for ASTM A193 Grade B5?
    The UNS designation for ASTM A193 Grade B5 is UNS S50100. This corresponds to 5% Cr-Mo. The UNS code is universal across ASTM, ASME (SA-193), PED 2014/68/EU and NORSOK material specifications.
    What is the service temperature range for Grade B5?
    B5 (5% Cr-Mo) is used for elevated-temperature service typically up to 550 °C (1022 °F), with creep-rupture data available to ASME B&PV Section II-D limits.